Mechanochemical <i>in situ</i> generated gas reactant for the solvent-free hydrogenation of porphyrins
نویسندگان
چکیده
The synthesis of chlorins was performed by hydrogenation porphyrins using diimide generated and consumed under mechanical activation. reaction conditions achievable ball milling, absence solvent use hydrazine hydrate as source, allowed the with high conversion, selectivity, nearly ideal sustainability scores (atom economy 97% E-factor 0.96).
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ژورنال
عنوان ژورنال: Green Chemistry Letters and Reviews
سال: 2021
ISSN: ['1751-7192', '1751-8253']
DOI: https://doi.org/10.1080/17518253.2021.1921283